M. Souto等人发现,以 tetrathiafulvalene (TTF)作为配体所得到的MOF(MUV-2)在溶剂填充下会发生可逆的结构收缩膨胀,其膨胀率最大可达单胞体积的40%。此外,这种极性配体的电化学性质会随着弯曲或拉伸发生变化,在电化学传感中具有一定的潜在应用价值。
Manuel Souto,Guillermo Minguez Espallargas*, et al. Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework. J. Am. Chem. Soc., DOI: 10.1021/jacs.8b05890
https://pubs.acs.org/doi/10.1021/jacs.8b05890