Uchida, R.等人研究了铯(Cs+)和铷(Rb+)在多元杂化钙钛矿太阳能电池中的作用。调查结果表明Cs+的含量小于10%可以掺入钙钛矿晶格里,Rb+因其离子半径过小,无法影响钙钛矿晶格。Rb+和过多的铯Cs+均会起到负面作用:非辐射复合增加,电池效率降低。
Uchida, R., Binet, S. et al. Insights about the Absence of Rb Cation from the 3D Perovskite Lattice: Effect on the Structural, Morphological, and Photophysical Properties and Photovoltaic Performance. Small.
Doi:10.1002/smll.201802033.
https://doi.org/10.1002/smll.201802033.