M. Miyamura等人以聚硅烷作为载体，负载RhPt金属纳米颗粒后装载于液流反应管中，在1 amt H2下催化芳烃加氢，表现出远高于搅拌反应的催化性能。该系统可以稳定运行超过50天，TON >3.4 × 105。如下图所示，该体系还可以控制选择性地催化多环芳烃中的单个芳环加氢。
Hiroyuki Miyamura, Shu Kobayashi*, et al. Polysilane-Immobilized Rh–Pt Bimetallic Nanoparticles as Powerful Arene Hydrogenation Catalysts: Synthesis, Reactions under Batch and Flow Conditions and Reaction Mechanism
J. Am. Chem. Soc., DOI: 10.1021/jacs.8b06015
https://pubs.acs.org/doi/10.1021/jacs.8b06015
