L. Liu等人发现Co²⁺和Zn²⁺离子可以沿着Mn-MOF (Et₄N)₂[Mn₂L₃] (H₂L = 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone)的c轴孔道扩散，取代Mn离子。Mn-MOF孔道中可以发生可逆的溶剂化和去溶剂化。在去溶剂化的Mn-MOF中金属离子的扩散速率可以提高2000倍。在溶剂化的Mn-MOF中可以得到部分交换的MOF。

Lujia Liu, T. David Harris*, et al. Harnessing Structural Dynamics in a 2D Manganese–Benzoquinoid Framework To Dramatically Accelerate Metal Transport in Diffusion-Limited Metal Exchange Reactions

J. Am. Chem. Soc., DOI: 10.1021/jacs.8b06774

https://pubs.acs.org/doi/10.1021/jacs.8b06774