中科院化学所何圣贵研究员课题组首次报道用双原子组分CuB+催化CH4和CO2偶联,并深入理解反应机理。质谱和DFT证实, CuB+首先催化CH4 生成中间态[HBCH2Cu]+, 然后与CO2偶联生成终产物乙烯酮。
Qiang Chen, Yan-Xia Zhao*, Sheng-Gui He*, et al. Coupling of Methane and Carbon Dioxide Mediated by Diatomic Copper Boride Cations [J]. Angew. Chem. Int. Ed. 2018
DOI: 10.1002/anie.201808780
下载链接: https://doi.org/10.1002/anie.201808780