魏茨曼科技学院Ronny Neumann教授课题组合成了硫脲配位的Re(Bipy)(CO)₃，并研究了其电催化还原CO₂的性能。后续研究发现，硫脲可作为CO₂配位的位点和质子给体，极大地促进了CO₂电还原为CO的活性，其TOF为3040 s^-1。

Eynat Haviv, Dima Azaiza-Dabbah, Ronny Neumann*, et al. A Thiourea Tether in the Second Coordination Sphere as a Binding Site for CO₂ and a Proton Donor Promotes the Electrochemical Reduction of CO₂ to CO Catalyzed by a Rhenium Bipyridine Type Complex[J]. J. Am. Chem. Soc.,2018

Doi: 10.1021/jacs.8b05658

下载链接：https://pubs.acs.org/doi/pdf/10.1021/jacs.8b05658