近日,美国贝鲁特大学Mohamad Hmadeh和Tarek H. Ghaddar团队成功将2,2':6',2''-三联吡啶-4'-(4-苯甲酸甲酯)钌(II) (Ru(cptpy)2引入MOFs,AUBM-4中。X-射线单晶分析发现,Ru(cptpy)2配合物与和O原子8配位的Zr原子连接成一维结构。作者进一步将该稳定的MOF用做光催化剂,该催化剂在可见光照下可高效的将CO2转化为HCOOH,转化速率可达366 µmol∙g-1∙h-1,且具有高的稳定性。
Mahmoud Elcheikh Mahmoud, Tarek H. Ghaddar*, Mohamad Hmadeh,* et al. Metal Organic Framework-Photocatalyst Incorporating Bis(4’-(4-Carboxyphenyl)-Terpyridine)Ruthenium(II) for Visible Light-Driven Carbon Dioxide Reduction. J. Am. Chem. Soc., 2019
DOI: 10.1021/jacs.9b01920
下载链接:https://pubs.acs.org.ccindex.cn/doi/10.1021/jacs.9b01920